博彩-玩博彩策略论坛

趙冰，博士，教授，畢業于天津大學。

人才稱號：黑龍江省應用化學領軍人才梯隊后備帶頭人

齊齊哈爾市應用化學領軍人才梯隊帶頭人

通訊地址：齊齊哈爾市文化大街42號化學與化學工程學院輕紡樓623

電話：0452-2738309

電子郵件：[email protected]

課題組網站：

研究領域：功能性共價有機框架的構建及應用研究

小分子熒光探針的設計及應用工程

招生學科：化學工程與技術(應用化學)，化學(物理化學)，材料與化工類

教育及科研經歷：

1995-1999年遼寧科技大學化工學院精細化工專業本科

2002-2005年天津大學理學院有機化學碩士

2005-2008年天津大學化工學院應用化學博士

2008年至今齊齊哈爾大學化學與化學工程學院學院碩士生導師

2015-2016年美國弗吉尼亞大學化學系訪問學者

2015年至今齊齊哈爾大學化學與化學工程學院學院教授

榮譽和獎勵

獎勵

1.雜環硫乙酰氨類杯[4]芳烴衍生物的合成及離子識別性能的研究，黑龍江省科學技術獎(自然科學類)三等獎，黑龍江省人民政府，2016-08-30。

2.基于稠環及多芳基咪唑長波長熒光探針的設計及接力識別性能研究，黑龍江省高校科學技術獎二等獎，黑龍江省高校科學技術委員會，2020-12-21。

榮譽

齊齊哈爾市第十屆優秀科技工作者

學術兼職：

中國化工學會精細化工專委會委員

黑龍江省化工學會第五屆理事會常務理事

黑龍江省工業和信息化廳專家庫專家

黑龍江省國資委投資咨詢專家庫專家

科研論文

1.Chunyu Bi,Bing Zhao*, Wang Zheng, Mo Sun, Wei Kan *, Liyan Wang, Li Sun, Xiuwen Wang, Ming Zhao*, Highly efficient adsorption and capture of prevalent phenolic contaminants from the real samples by trifluoromethyl-functionalized covalent organic frameworks,Separation and Purification Technology, 2024, 339, 126631 (DOI: 10.1016/j.seppur.2024.126631).

2.Pengfei Zhang, Jin Qi, Ran Zhang, Yifan Zhao, Jingyu Yan, Yajuan Gong, Xiaoming Liu, Binbin Zhang, Xiao Wu, Xiuping Wu, Cheng Zhang,BingZhao*, Li Bing, Recent advances in composite hydrogels: synthesis, classification, and application in the treatment of bone defects,Biomaterials Science, 2023, 12, 2, 308-329 (DOI: 10.1039/d3bm01795h)

3.Qiushuang Li,Bing Zhao*, Xiangdong Kong a, Liyan Wang, Wei Kan, Bo Song, Rui Yu a, Pengfei Zhang，Multi-responsive fluorescent covalent organic framework based on phenanthro[9,10-d]imidazole moiety for relayed detection of Cu2+/Al3+ followed by PO₄^3–and its applications，Dyes and Pigments, 2024, 222, 111886(DOI:10.1016/j.dyepig.2023.111886)

4.Lin Yue, Jiayu Zhang, Zhihao Zeng, Chunran Zhao, Xin Hu, Leihong Zhao,Bing Zhao*,and Yiming He*, In situ fabrication of an S‐scheme nanbo3/Bi₂O₂CO₃heterojunction for enhanced performance in photocatalytic nitrogen fixation,Langmuir, 2023, 39, 13267?13278(DOI: 10.1021/acs.langmuir.3c01725)

5.Rui Yu, Wei Kan,*, Xin Qi, Yue Zhang, Limin Ding,*, Liyan Wang,Bing Zhao,*An ICT phenanthro[9,10-d]imidazole-based fluorescence probe with aggregated characteristic for colorimetric detection of hypochlorous acid and its applications in water samples andliving cells,Inorganica Chimica Acta, 2023, 558,121724(DOI:10.1016/j.ica.2023.121724)

6.Shaoxin Li,Bing Zhao*, Wei Kan*, Tianshu Song, Wang Zheng, Xin Qi, Liyan Wang, Bo Song, A fluorescent covalent organic framework with a brick-wall topology for the detection of Cu2+ promoted by the associated mechanism,Dyes and Pigments, 2023, (214), 111178, (DOI: 10.1016/j.dyepig.2023.111178)

7.Huagen Liang, Zejia Gai, Fu Chen, Shengyu Jing*, Wei Kan,Bing Zhao*, Shibin Yin, Panagiotis Tsiakarasf, Fe3C decorated wood-derived integral N-doped C cathode for rechargeable Li-O2 batteries,Applied Catalysis B: Environmental, 2023, 324, 122203 (DO: 10.1016/j.apcatb.2022.122203)

8.Zhigang Li,Bing Zhao*, Wei Kan*, Fanqiang Bu, Xin Qi, Liyan Wang, Bo Song, Limin Ding. An acid-triggered reactive and enhanced fluorescent probe for selective detection of Al3+/H+ and its application in real water samples and living cells,Journal of Fluorescence, 2023, 33, 91–101 (DOI:10.1007/s10895-022-03039-5)

9.Wang Zheng?, Anran Li?, Xiuwen Wang*, Zhigang Li,Bing Zhao*,Liyan Wang, Wei Kan*, Li Sun, Xin Qi. Construction of hydrophilic covalent organic frameworks and their fast and efficient adsorption towards cationic dyes from aqueous solution,New Journal of Chemistry, 2022, 46, 22185–22194 (DOI: 10.1039/d2nj04336j)

10.Lantian Li,? Anran Li,?Bing Zhao*, Wei Kan*, Chunyu Bi, Wang Zheng, Xiuwen Wang, Li Sun, Liyan Wang and Hongrui Zhang. Multi-sulfonated functionalized hydrophilic covalent organic framework for highly efficient dye removal from real samples, New Journal of Chemistry, 2022, 46, 17016–17025 (DOI: 10.1039/d2nj02857c)

11.李安然,趙冰*,闞偉*,宋天舒,孔祥東,卜凡強,孫立,殷廣明,王麗艷.基于菲并咪唑ON?OFF?ON雙比色熒光探針及細胞成像.高等學校化學學報, 2021, 42(8), 2403–2411 (DOI: 10.7503/cjcu20210089)

12.Jiahui Du,Bing Zhao*, Wei Kan*, Haochun Yin, Tianshu Song, Liyan Wang, Li Sun, Xiuwen Wang, Guangming Yin and Jianxin Wang. A phenanthrene[9,10-d]imidazole-phenol-based fluorescent probe combined ESIPT and AIE for “turn-on” detection of Cu²⁺with a green-emitting and improved stokes shift and its application.New Journal of Chemistry, 2021, 45(34), 15415–15422 (DOI: 10.1039/D1NJ02177J)

13.Fanqiang Bu,Bing Zhao*, Wei Kan*, Limin Ding*, Ting Liu, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. An ESIPT characteristic “turn-on” fluorescence sensor for Hg²⁺with large Stokes shift and sequential “turn-off” detection of S^2–as well as the application in living cells.Journal of Photochemistry & Photobiology A: Chemistry, 2020, 387, 112165, (DOI: doi.org/10.1016/j.jphotochem.2019.112165).

14.Haochun Yin,Bing Zhao*, Wei Kan*, Limin Ding*, Liyan Wang, Bo Song, Wenbo Wang, Qigang Deng. A phenanthro[9,10-d]imidazole-based optical sensor for dual-responsive turn-on detection of acidic pH and Cu²⁺in chicken blood and living cells.Dyes and Pigments, 2020, (173), 107916, (DOI:0.1016/j.dyepig.2019.107916).

15.Yuqian He,Bing Zhao*, Wei Kan*, Limin Ding*, Zhaochuan Yu, Mingyue Wang, Bo Song and Liyan Wang. Two isomeric and distinguishable H2S fluorescence probes for monitoring spoilage of eggs and visualizing exogenous and endogenous H₂S in living cells.Analyst, 2020, 145, 213–222 (DOI: 10.1039/c9an01629e).

16.何玉倩，趙冰*，闞偉*，王麗艷，宋波，殷廣明，畢野，陳書文.基于ESIPT和AIE活性的菲并咪唑Fe³⁺熒光探針及細胞成像研究.有機化學，2019, 39(11), 3250–3257(DOI: 10.6023/cjoc201904078).

17.Bing Zhao *, Yuqian He, Wei Kan *, Fengqiao Kong, Liyan Wang, Bo Song, Wenbo Wang, Guangming Yin, Jianxin Wang. SelectiveN-alkylation of 2-amino-4H-chromene-3-carbonitrile derivatives with alcohols catalyzed by AlCl₃under the assistance of CH₃COOH,Chemical Research in Chinese Universities, 2019, 35 (6), 997–1001 (DOI: 10.1007/s40242-019-9248-5).

18.Bu Fanqiang,Zhao Bing*, Kan Wei*, Wang Liyan, Song Bo, Wang Jianxin, Zhang Zhe, Deng Qigang, Yin Guangming. A phenanthro[9,10-d]imidazole-based AIE active fluorescence probe for sequential detection of Ag⁺/AgNPs and SCN^–in water and saliva samples and its application in living cells,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.117333).

19.白雨弘旭，趙冰*，何玉倩，楊宜璇，葛薇，陳明明，張立鑫.增強型四苯基咪唑類熒光探針及其對硫醇的識別性能.精細石油化工, 2019,36(4), 79–84.

20.Haochun Yin,Bing Zhao*, Wei Kan*, Ting Liu, Wenbo Wang, Guangming Yin, Wang Liyan, Gao Yan*, Wang Jianxin. Hydroxyl phenyl imino modified phenanthro[9,10-d] imidazole: An AIEE-active sensor for determination of Cu²⁺in water samples and subsequent "turn-on" recognition of Cr³⁺with logic gates,Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019, 217, 18–26 (DOI: 10.1016/j.saa.2019.03.060).

21.Wei Wang, Jian Wu, Qinglei Liu, Gao Yan, Huimin Liu,Bing Zhao. A highly selective coumarin-based chemosensor for the sequential detection of Fe³⁺and pyrophosphate and its application in living cell imaging.Tetrahedron Letters, 2018, 59(19), 1860–1865.

22.趙冰*，何玉倩，闞偉*，李少鑫，王麗艷，闞宏澤，劉雙義.基于熒光素-羅丹明B的比色探針對Cu2+和EDTA的接力識別.精細石油化工, 2018，35(5), 60–65.

23.李少鑫，闞偉*，趙冰*，李慧婷，王麗艷，劉雙義，闞宏澤.基于熒光素-羅丹明B的雙Schiff堿選擇性紫外識別Fe³⁺的探針.精細石油化工, 2018, 35(2), 58–63.

24.Shaoxin Li, Wei Kan*,Bing Zhao*, Liu Ting, Fang Yue, Bai Liming and Wang Liyan, A fluorescent pH probe for an aqueous solution composed of 7-hydroxycoumarin, Schiff base and phenanthro[9,10-d]imidazole moieties (PICO).Heterocyclic Communications, 2018, 24(2), 93–97 (DOI: 10.1515/hc-2017-0174).

25.Shaoxin Li, Bing Zhao*, Wei Kan, Liyan Wang, Bo Song, and Shuwen Chen*. A off–on pH fluorescence probe derived from phenanthro[9,10-d] imidazol-fluorescein based on ESIPT and ICT,Research on Chemical Intermediates, 2018, 44(1), 491–502. (DOI: 10.1007/s11164-017-3115-0) (IDS No: FS2LC).

26.Bing Zhao *, Ting Liu, Yue Fang, Liyan Wang, Wei Kan, Qigang Deng *, and Bo Song. A new selective chemosensor based on phenanthro[9,10-d] imidazole-coumarin with sequential “on-off-on” fluorescence response to Fe³⁺and phosphate anions and its application in live cell,Sensors & Actuators: B. Chemical, 2017, 246, 370–379. (DOI: 10.1016/j.snb.2017.02.079).

27.李少鑫，闞偉*，趙冰*，白麗明，劉婷，王麗艷，宋波.氨基乙酰肼鏈接的熒光素-菲并咪唑衍生物的合成與表征.精細石油化工, 2017, 34(5), 26–31.

28.孔鳳巧，趙冰*，姜黎黎，王麗艷，鄧啟剛.微波輻射下合成1,3-二取代苯基-3-(苯并噻唑-2-氨基)-1-丙酮衍生物.精細石油化工, 34(3), 2017, 1–7.（2017-05-18）

29.劉婷，趙冰*，李少鑫，房躍，王麗艷，宋波.乙酰氨基鏈接的菲并[9,10-d]咪唑-香豆素衍生物的合成.化學研究與應用, 2017, 29(7), 999–1005.

30.趙冰*，劉婷，王麗艷，鄧啟剛. Schiff堿鏈接的雙菲并咪唑Fe3+熒光探針的合成及識別性能研究.化學試劑,2017,39(1),1–5;10.

31.趙冰*，李少鑫，馬明杰，鄧啟剛，王麗艷，闞偉，馮亞青.含乙氧甲酰甲氨基咪唑杯[4]芳烴的合成及其水相體系中對Al3+和Ag+的熒光識別.精細化工,2016,33(10),1189–1194(DOI:10.13550/j.jxhg.2016.10.019 ).

32.Bing Zhao*, Ting Liu, Yue Fang, Liyan Wang, Song Bo and Deng Qigang*. Two “turn-off” Schiff-base fluorescence sensors based on phenanthro [9,10-d]imidazole-coumarin derivatives for Fe³⁺in aqueous solution,Tetrahedron Letters, 2016, 57(39), 4417–4423 (DOI: 10.1016/j.tetlet.2016.08.064).

33.Bing Zhao*, Yue Fang, Yu Xu, Qigang Deng, Ting Liu, Wei Kan, and Liyan Wang. Dual-responsive pH sensor based on a phenanthro[9,10-d]imidazole fluorophore modified by amino diacetate.Tetrahedron Letters, 2016, 57(16), 1825–1830 (DOI: 10.1016/j.tetlet.2016.03.046).

34.Bing Zhao*, Yu Xu, Qigang Deng, Wei Kan, Yue Fang, Liyan Wang, Yan Gao. Modified 1H-phenanthro[9,10-d]imidazole derivative with the double acetohydrazide as fluorescent probe for sequential detection of Ni²⁺and Al³⁺with ‘on–off–on’ response.Tetrahedron Letters, 2016, 57(8), 953–958 (DOI: 10.1016/j.tetlet.2016.01.065)

35.趙冰*，姜黎黎，鄧啟剛，王麗艷，宋波.一鍋三組分合成2取代-1,4-2H-咪唑并[4,5-b]吲哚衍生物.化學世界,2016,57(1),43–47.

36.Wei Kan, Tao Jing, Xiaohong Zhang, Yongjie Zheng, Lin Chen,Zhao Bing*. Microwave-assisted one pot synthesis ofN-substituted 2-methyl -1H-pyrrole-3-carboxylate derivatives without catalyst and solvent,Heterocycles, 2015, 91(12), 2367–2376 (DOI: 10.3987/COM-15-13340).

37.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng, Liyan Wang, Bo Song, Yan Gao. Microwave-assisted Michael addition of 2-amino pyridine to chalcones under catalyst-free conditions,Research on Chemical Intermediates, 2015, 41, 5809–5819 (DOI: 10.1007/s11164-014-1703-9).

38.Bing Zhao, Yu Xu, Mingjie Ma, Qigang Deng. A selective fluorescence probe for copper(II) ion in aqueous solution based on 4-(1,4,5-triphenyl-1H-imidazol-2- yl)anilinyl acetates,Research on Chemical Intermediates, 2015, 41, 8031–8040 (DOI: 10.1007/s11164-014-1875-3).

39.Bing Zhao, Yue Fang, Mingjie Ma, Qigang Deng, Yu Xu, Liyan Wang. A new on-fluorescent sensor for Ag⁺based on benzimidazole bearing bis(ethoxycarbonyl methyl)amino groups.Heterocyclic Communications, 2015, 21(4), 211–214 (DOI: 10.1515/hc-2015-0002).

40.Bing Zhao, Yu Xu, Yue Fang, Liyan Wang Qigang, Deng. Synthesis and fluorescence properties of phenanthro[9,10-d] imidazole derivative for Ag⁺in aqueous media.Tetrahedron Letters, 56(19), 2015, 2460–2465. (DOI: 10.1016/j.tetlet.2015.03.094).

41.趙冰,馬明杰,阮耀宇,王麗艷,闞偉,宋波,石克炘.含氨基乙酸酯苯并咪唑杯[4]芳烴熒光分子探針的合成及光譜性能.化學試劑, 2015,37（6）,545–548；560.

42.Bing Zhao, Yu Xu, Qigang Deng, Zhuo Liu, Liyan Wang, Yan Gao. One-pot, three component synthesis of novel 5H-[1,3,4]thiadiazolo[3,2-a]pyrimidine- 6-carboxylate derivatives by microwave irradiation.Tetrahedron Letters, 2014, 55(33), 4521–4524 (DOI: 10.1016/j.tetlet.2014.06.073).

43.Bing Zhao, Lili Jiang, Zhuo Liu, Qigang Deng*, Liyan Wang, Song Bo, and Gao Yan, A microwave assisted synthesis of highly substituted 7-methyl- 5H-thiazole[3,2-a]pyridmidine -6-carboxylate derivatives via one pot reaction of aminothiazole, aldehyde and ethyl acetoacetate.Heterocycles, 87(10), 2013, 2093–2102 (DOI: 10.3987/COM-13-12797)

44.Bing Zhao, Yaoyu Ruan, Mingjie Ma, Qigang Deng*, Liyan Wang, Yaqing Feng, and Yan Gao. One-pot synthesis of 11,23-bis(imidazol-1-yl)calix[4]arene derivatives based on the upper rim of bis-aminocalix[4]arene.Heterocycles, 2013, 87(9), 1917–1924 (DOI: 10.3987/COM-13-12771).

45.Bing Zhao, Yacui Zhou, Mengjiao Fan, Zhiyu Li, Liyan Wang, Qigang Deng. Synthesis, fluorescence properties and selective Cr(III) recognition of tetraaryl imidazole derivatives bearing thiazole group.Chinese Chemical Letters, 2013, 24, 257–259 (DOI: 10.1016/j.cclet.2013.01.031).

46.Bing Zhao, Yaoyu Ruan, Qigang Deng, Liyan Wang, Bo Song and Yaqing Feng. Synthesis and characterization of heteroarylthio derivatives of 5, 17-di-tert-butyl-11, 23-diamido-25, 27-diprotected calix[4]arene.Heterocyclic Communication, 2013, 1, 19–22 (DOI: 10.1515/hc-2012-0154).

47.Bing Zhao, Mengjiao Fan, Zhuo Liu, Lifeng Hu, Bo Song, Liyan Wang and Qigang Deng.Reformatsky reaction promoted by an ionic liquid ([Bmim]Cl) in the synthesis ofβ-hydroxyl ketone derivatives bearing a coumarin unit,Journal of Chemical Research, 2012, 6, 393–395 (DOI: 10.3184/174751912X13371 652436057).

科研項目

1.硫酸鉀制粒項目實施關鍵技術攻關與轉化，項目負責人，黑龍江省省屬高等學校基本科研業務費科研項目，2023—2025。

2.新型“雙響應”熒光共價有機框架的構建及響應機制研究，項目負責人，國家自然科學基金面上項目，2021—2024。

3.熒光型共價有機框架材料的設計及生物學響應特征研究，項目負責人，黑龍江省重點研發計劃指導項目，2021—2023。

4.基于AIEE和ESIPT的菲并咪唑白光探針的設計和性能研究，項目負責人，黑龍江省級領軍人才梯隊后備帶頭人資助項目，2018—2021。

5.基于多重響應機理協同作用的雙光子熒光探針的合成及識別性能研究，項目負責人，黑龍江省省屬高等學校基本科研業務費科研項目，2018—2020。

6.基于熒光探針法檢測酒類飲品中Cu2+含量的研究，項目負責人，黑龍江省省屬高等學校基本科研業務費科研項目（植物性食品加工技術特色學科專項），2018—2020。

7.基于稠(多)芳基咪唑tweezers結構熒光分子的構建及其識別性能研究，項目負責人，黑龍江省科學基金留學歸國人員科學基金項目，2017—2020。

8.基于稠環及多芳基咪唑長波長熒光分子探針的設計及接力識別性能研究，項目負責人，國家自然基金青年科學基金項目，2016—2018。

9.基于杯芳烴的多芳基咪唑雙功能熒光分子探針的設計合成及性能研究，項目負責人，黑龍江教育廳面上項目，2014—2015。

10.雜環硫乙酰氨類杯[4]芳烴衍生物的合成及離子識別性能的研究，項目負責人，黑龍江省科技廳青年基金項目，2010—2012。

專利

1.趙冰，李秋爽，李元琪，李蘭天，闞偉，王麗艷，王秀文，孫立，杜研，沈思宇，沈曉亮。一種雜原子摻雜共價有機框架材料及其制備方法與應用，發明專利，專利號ZL 2022 1 0842324.4，授權日期2024.02。

2.趙冰，卜凡強，宋天舒，闞偉，王文波，殷廣明，王麗艷。一種裸眼或熒光檢測Ag⁺雙菲并咪唑探針及使用方法，發明專利，專利號ZL201811192860.4，授權日期2021.01。

3.趙冰，卜凡強。一種裸眼或熒光Al3+探針及其制備方法和應用，發明專利，ZL 201911000088.6，授權日期2023.09。

4.趙冰，李秋爽，李元琪，孔祥東，闞偉，王麗艷，王秀文，孫立，杜研，沈思宇，沈曉亮。一種Cu2+和Al3+雙功能熒光共價有機框架材料及其制備方法和應用，發明專利，ZL 2022 1 0740307.X，授權日期2023.07。

5.趙冰，鄭旺，李志剛，趙立杰，闞偉，王麗艷，孫立，王秀文。一種用于對苯二酚吸附的共價有機框架材料及其制備方法和應用，發明專利，ZL202111515003.5，授權日期2023.06。

6.趙冰，李志剛，闞偉，李安然，鄭旺，卜凡強，王麗艷，宋波，孫立，王秀文。一種實時檢測亞硫酸氫根離子的熒光探針及其制備方法與應用，發明專利，ZL 202111542466.0，授權日期2023.03。

7.趙冰，李安然，孔祥東，杜佳慧，闞偉，卜凡強，王麗艷，孫立，王秀文。一種光譜法和比色法檢測不同形式碘的分子平臺及其制備方法和應用，發明專利，ZL202010794666.4，授權日期2022.08。

8.趙冰，宋天舒，李安然，孔祥東，闞偉，王麗艷，孫立，王秀文。一種Cu2+熒光共價有機框架材料及其制備和應用，發明專利，ZL 202110170647.9，授權日期2022.06。

9.趙冰，卜凡強，宋天舒，闞偉，王文波，殷廣明，王麗艷。一種裸眼或熒光檢測Ag+雙菲并咪唑探針及使用方法，發明專利，ZL2018 1 1192860.4，授權日期2021.01。

10.趙冰，劉婷，孔鳳巧，李少鑫，闞偉，王麗艷。可逆雙羥基菲并咪唑Hg2+熒光探針及其合成與使用方法，發明專利，ZL201611019074.5，授權日期2020.08。

11.趙冰，孔鳳巧，卜凡強，李少鑫，劉婷，王麗艷，闞偉，宋波。一種Lewis/Bronsted酸促進下醇參與的2-氨基色烯衍生物N-烷基化方法，發明專利，專利號ZL201710255046.1，授權日期2019.06。

12.趙冰，卜凡強，何玉倩，李少鑫，尹浩純，闞偉，王麗艷。一種用于裸眼檢測的熒光素-羅丹明B銅離子紫外分子探針及其合成和使用方法，發明專利，專利號ZL201711088730.1，授權日期2019.05。

13.趙冰，宋波，李少鑫，孔鳳巧，劉婷，闞偉，王麗艷。三羥基咪唑-熒光素pH熒光探針及其制備方法，發明專利，專利號ZL201611047563.1，授權日期2019.05。

14.趙冰，劉婷，鄧啟剛，王麗艷，闞偉，宋波。雙Schiff堿鏈接的對稱型菲并咪唑Fe³⁺熒光探針及制備方法，發明專利，專利號ZL201610201233.7，授權日期2017.09。

15.趙冰。一種用于鐵離子檢測的菲并咪唑-香豆素雙熒光基團比率熒光分子探針及其合成和使用方法，發明專利，專利號ZL201510785171.4，授權日期2017.04。

16.趙冰，阮耀宇，闞偉，王麗艷，鄧啟剛。一種多取代咪唑杯芳烴衍生物及制備方法，發明專利，專利號ZL 201310015856.1，授權日期2015.09。

17.趙冰，闞偉，劉卓，王麗艷，宋波，鄧啟剛。一鍋法合成噻唑并[3,2-a]嘧啶類衍生物的方法，發明專利，專利號ZL201310016623.3，授權日期2015.04。

18.趙冰，闞偉，劉卓，王麗艷，鄧啟剛。一種多取代噻二唑并[3,2-a]嘧啶-6-羧酸酯衍生物的微波合成方法，發明專利，專利號ZL201310052797.5，授權日期2015.02。

19.鄧啟剛，陳朝暉，趙冰。一種亞麻織物后整理工藝，發明專利，專利號ZL 2009 1 0071368，授權日期2012.08。

專著或教材

1.宋波，闞偉，趙冰.淀粉化學品，哈爾濱工程大學出版社，2009.08。

2.趙冰.有機化學反應與有機材料研究，中國水利水電出版社，2014.10。